Transformation of Zn and Cr during co-combustion of sewage sludge and coals: influence of coal and steam.

Combustion experiments of sewage sludge (SS) blended with low-rank coal were conducted through a drop tube furnace (DTF) to explore the effects of low-rank coal type, blending ratio, and steam on the transformation of Zn and Cr. The results showed that the retention rates of Zn and Cr in ash increased from 24.35% and 71.49% for sludge combustion alone to 53.77% and 117.49%, respectively, for coal blended to SS with a mass ratio of 7:3. The greater the proportion of low-rank coal in the fuel, the greater the residual rate of heavy metals in the ash. Meanwhile, rapid diffusion of vapor occupied adsorption sites on metal mineral surfaces, reducing the retention of Zn and Cr in the co-combustion ash. The leaching toxicity analysis of ash showed that the co-combustion ash of SS with coal was free from leaching toxicity hazards in simulated scenarios. The extraction rate of Zn in co-combustion ash increased from 90.72% with hydrothermal acid leaching to 95.46% with microwave-assisted in 2 mol/L H2 SO4 extract. The extraction rate of Cr in hydrothermal acid leaching was 62.80%, which was much higher than that in microwave-assisted extraction (31.76%).