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Selective C-H trifluoromethylation of benzimidazoles through photoredox catalysis.
Chemical Communications : Chem Comm 2017 January 18
The protocol presented here is a new strategy for visible light induced C-H trifluoromethylation at C4 of benzimidazoles using Togni's reagent in the presence of fac-Ir(ppy)3 . Its advantages are its operational simplicity, mild reaction conditions, low catalyst loading and wide substrate scope in which electron-withdrawing, electron-donating groups and different protecting groups are tolerated.
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