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A dynamic covalent approach to [Pt n L 2 n ] 2 n + cages.

Quinn V C van Hilst, Aston C Pearcy, Dan Preston, L James Wright, Christian G Hartinger, Heather J L Brooks, James D Crowley
Chemical Communications : Chem Comm 2024 March 27
A dynamic covalent approach was exploited to generate a family of homometallic [Pt n L2 n ]2 n + cage (predominantly [Pt2 L4 ]4+ systems) architectures. The family of platinum(II) architectures were characterized using 1 H nuclear magnetic resonance (NMR) and diffusion ordered spectroscopy (DOSY), electrospray ionization mass spectrometry (ESI-MS) and the molecular structures of two cages were determined by X-ray crystallography.

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