Crystal and magnetic structures of R 2 Ni 2 In compounds (R = Tb and Ho).

Crystal and magnetic structures of R2 Ni2 In (R = Tb and Ho) have been studied using powder neutron diffraction at low temperatures. The compounds crystallize as orthorhombic crystal structures of the Mn2 AlB2 type. At low temperatures, the magnetic moments localized solely on the rare earth atoms form antiferromagnetic structures. The Tb magnetic moments, equal to 8.8 (4) μB and parallel to the c axis, form a collinear magnetic structure described by the propagation vector k = [½ , ½ , ½]. This magnetic structure is stable up to the Néel temperature TN = 40 K. For Ho2 Ni2 In a complex, temperature-dependent magnetic structure is detected. In the temperature range 6.1-8.6 K, an incommensurate sinusoidal magnetic structure, described by the propagation vector k1 = [0.24, 1, 0.52] is observed, while in the temperature interval 2.2-2.5 K a square-modulated magnetic structure, related to k2 = [0.17,{{5} \over {6}},{{1} \over {2}}] (the component along the a axis slightly differs from the commensurate value) and its third harmonics 3k2 = [0.50,{{5} \over {2}},{{3} \over {2}}] is found. At 3.1-3.7 K as well as below 2 K, a coexistence of both detected magnetic structures is observed. The Ho magnetic moments remain parallel to the c axis in both the sine- and square-modulated magnetic structures. The low-temperature heat capacity data confirm a first-order transition near 3 K.