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Diastereoselective Intramolecular Cyanoamidation with Alkenes.
European Journal of Organic Chemistry 2017 January 4
Reported herein is a diastereoselective intramolecular alkene cyanoamidation, wherein high d.r. values are imparted by chiral directing groups. Lactams with an α-all-carbon quaternary stereocenter are readily synthesized, which may enable access to structures frequently found in biologically active molecules and natural products.
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