We have located links that may give you full text access.
Infrared and Raman active vibrational modes in MoS 2 -based nanotubes: Symmetry analysis and first-principles calculations.
Journal of Computational Chemistry 2018 October 6
The possibility to use the axial point group dynamical representations for the infrared and Raman active modes classification in nanotubes is analyzed. The method proposed allows one to obtain the results of phonon symmetry analysis for nanotubes in Mulliken designations, which are traditional for molecules and crystallographic point groups. The approach suggested is applied to the phonon symmetry analysis in the single-wall carbon and MoS2 -based nanotubes. First-principles calculations of phonons in a bulk MoS2 crystal and a monolayer S-Mo-S are made. The results obtained are in reasonable agreement with the existing experimental data and other published results. The first-principles calculations of the phonon frequencies for armchair and zigzag MoS2 nanotubes are performed for the first time. It is shown that the number of infrared and Raman active modes becomes fixed starting from the relatively small nanotube diameters. The correlation of the phonon modes of MoS2 nanotubes with diameters up to 3.64 nm with phonon modes of the S-Mo-S monolayer is analyzed. It is demonstrated that the interpretation of the nature of nanotube A-type modes in the crystallographic factorization of the line group L = TF is the same as for m = 0 modes in the "polymer type" factorization L = ZP where P is the subgroup of the isogonal point group F, T is the translation subgroup of line group and the cyclic group Z includes the one-dimensional translations and the rotations around the screw axes or the reflections in the glide planes. © 2018 Wiley Periodicals, Inc.
Full text links
Related Resources
Trending Papers
Review article: Recent advances in ascites and acute kidney injury management in cirrhosis.Alimentary Pharmacology & Therapeutics 2024 March 26
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app
All material on this website is protected by copyright, Copyright © 1994-2024 by WebMD LLC.
This website also contains material copyrighted by 3rd parties.
By using this service, you agree to our terms of use and privacy policy.
Your Privacy Choices
You can now claim free CME credits for this literature searchClaim now
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app