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Synthesis of an azulene-containing graphene nanoribbon.

The solution-phase synthesis of a non-benzenoid nanoribbon from an azulene-containing polymer via alkyne benzannulation is reported. The nanoribbon is soluble in common organic solvents and exhibits conductivity values up to 1.5 × 10-3 S cm-1 once doped by protonation in the thin film state.

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