Hydrothermal synthesis of NiO nanoparticles decorated hierarchical MnO 2 nanowire for supercapacitor electrode with improved electrochemical performance.

In this work, MnO2 /NiO nanocomposite electrode materials have been synthesized by a cost-effective hydrothermal method. The effect of the concentrations (0, 1, 3, 5, and 7 wt%) of NiO nanoparticles on the surface morphology, structural properties, and electrochemical performance of the nanocomposites was characterized by different characterization techniques. The scanning electron micrographs (SEM) reveal that the as-prepared NiO nanoparticles are well connected and stuck with the MnO2 nanowires. The transmission electron microscopy (TEM) analysis showed an increase in the interplanar spacing due to the incorporation of NiO nanoparticles. The different structural parameters of MnO2 /NiO nanocomposites were also found to vary with the concentration of NiO. The MnO2 /NiO nanocomposites provide an improved electrochemical performance together with a specific capacitance as high as 343 F/g at 1.25 A/g current density. The electrochemical spectroscopic analysis revealed a reduction in charge transfer resistance due to the introduction of NiO, indicating a rapid carrier transportation between the materials interface. The improved electrochemical performance of MnO2 /NiO can be attributed to good interfacial interaction, a large interlayer distance, and low charge transfer resistance. The unique features of MnO2 /NiO and the cost-effective hydrothermal method will open up a new route for the fabrication of a promising supercapacitor electrode.