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Journal Article
Review
α-Boryl Carbanions: The Influence of Geminal Heteroatoms in C-C Bond Formation.
Chemical Record : An Official Publication of the Chemical Society of Japan ... [et Al.] 2024 Februrary 3
The wide applications of alpha-boryl carbanions in selective coupling with organohalides, imines/carbonyls and conjugated unsaturated substrates has become an interesting tool for organic synthesis. Strategically, the inclusion of heteroatoms, such as Si, S, N, F, Cl, Br and I in the alpha position opens a new venue towards multifunctionalities in molecular design. Here, a conceptual and practical view on powerful carbanions, containing α-silicoboron, α-thioboron, α-haloboron and α-aminoboron is given, as well as a prespective on their efficient application for selective electrophilic trapping.
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