Phase-transition materials derived photonic metamaterials for passively dynamic solar thermal and coldness harvesting.

The rising need for energy to actively heat and cool human-made structures is contributing to the growing energy crisis and intensifying global warming. Consequently, there's a pressing need for a sustainable approach to temperature management that minimizes energy consumption and carbon emissions. The substantial temperature differences between the Sun (approximately 5800 K), Earth (around 300 K), and outer space (about 3 K) offer a unique opportunity for passive thermal regulation on a global scale. Recent research indicates the possibility of addressing this issue through various low-carbon, passive technologies such as solar heating and radiative cooling. However, their practical application is often limited to certain seasons and climatic regions due to their static and single-function nature in managing temperature. In this context, we introduce a concept of phase-change metamaterials that provide passive, dynamic, and adjustable radiative thermal control, suitable for widespread engineering applications. Our designed metafilm comprises a Polydimethylsiloxane (PDMS) layer infused with vanadium dioxide (VO2 ) nanoparticles, backed by a layer of broadband-reflective silver (Ag). This metafilm exhibits a self-adjusting solar absorptance, shifting from 0.96 to 0.25 at a pivotal temperature while maintaining a nearly constant thermal emittance. We can finely tune the metafilm's optical characteristics by altering the VO2 nanoparticle concentration and PDMS layer thickness. To demonstrate its efficacy in solar thermal management and radiative cooling, we simulate its temperature behavior under various weather conditions.