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Selective dehydrogenation of ammonia borane to polycondensated BN rings catalysed by ruthenium olefin complexes.
Chemical Communications : Chem Comm 2024 January 3
Dehydrogenation of ammonia borane to well-defined products is an important but challenging reaction. A dinuclear ruthenium complex with a Ru-Ru bond bearing a diazadiene (dad) unit and olefins as non-innocent ligands catalyzes the highly selective formation of conjugated polycondensed borazine oligomers (B x N x H y ), predominantly B21 N21 H18 , the BN analogue of superbenzene.
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