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Highly selective conversion of CO 2 to para -xylene over tandem catalysts.

Yuanzhi Qu, Zelong Li, Hanwen Hu, Siyu Chen, Jijie Wang, Can Li
Chemical Communications : Chem Comm 2023 May 32
ZnZrO/Mg-Si-ZSM-5 tandem catalysts enable CO2 hydrogenation to para -xylene (PX) with PX selectivity up to 28% and a proportion of PX in xylene up to 84%. SiO2 and MgO modification increases the PX selectivity by reducing the Brønsted acid sites and reducing the pore size of the zeolite.

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