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Journal Article
Review
Structural authentication of intermediates of mechanistic significance in palladium- and nickel-catalysed cross-couplings: case studies.
Chemical Communications : Chem Comm 2023 April 12
This article examines a selection of case studies that highlight key strategies that have enabled the structural authentication of important species that shed light on fundamental on-cycle intermediates in palladium- and nickel-catalysed C-C, C-N, and C-O cross-coupling reactions. Particular emphasis is placed on studies in which the structures of rather intractable intermediates have been confirmed unambiguously by X-ray crystallography, while also contextualising the mechanistic insights that these reports have contributed.
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