Two-way long-range atmospheric transport of organochlorine pesticides (OCPs) between the Yellow River source and the Sichuan Basin, Western China.

This study revealed a two-way long-range atmospheric transport of organochlorine pesticides (OCPs) rather than a single mode, in Western China. Soil and air samples were collected along a transect with length of ca. 1000 km between the Yellow River source in the Qinghai-Tibet Plateau and the Sichuan Basin. Concentrations of ΣOCPs in soils and air were detected to be 175-69,229 (median 567) pg/g dry weight and 33.6-271 (median 98.3) pg/m3 , respectively. HCB, HCHs, DDTs, and SULPHs (sum of Endosulfan-I, Endosulfan-II and Endosulfan sulfate) were dominant. Isomeric ratios suggested dominant weathered technical HCH, technical DDT and chlordane profile, and confirmed the current-use of Endosulfan along the transect. Furthermore, local fresh input of Lindane and possible illegal use of technical DDT might occur in the basin area. Based on isomeric and metabolic ratios, fractionation and principal component analysis, a two-way transport system was determined. One flowed from the Sichuan Basin to the Qinghai-Tibet Plateau comprising HCB, HCHs, and DDTs, while the other flowed reversely from the Qinghai-Tibet Plateau to the Sichuan Basin dominating by SULPHs and CHLs (including Heptachlor, Heptachlor epoxide, trans-chlordane, and cis-chlordane). Multiple linear regression analysis demonstrated greater average contributions of the Sichuan Basin sources onto the soil ΣOCPs than that of the Qinghai-Tibet Plateau source. Distinct from the single long-range atmospheric transport, our results highlighted the different source-sink roles of the Qinghai-Tibet Plateau and the Sichuan Basin for different OCP compounds.