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A semiconducting metal-chalcogenide-organic framework with square-planar tetra-coordinated sulfur.
Chemical Communications : Chem Comm 2018 October 15
We demonstrated here a novel semiconducting metal-chalcogenide-organic framework (MCOF-89) with an optical bandgap through the unlikely assembly between a metal chalcogenide unit and carboxylic acid. The elusive metal-chalcogenide unit [Mn4 (μ4 -S)] with square-planar tetra-coordinated sulfur (sptS) is for the first time observed in MOFs.
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