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Total Synthesis of the Highly N -Methylated Peptides Carmabin A and Dragomabin.
Marine Drugs 2018 September 18
The first total synthesis of carmabin A and dragomabin was achieved at 52.3 mg and 43.8 mg scale, respectively. The synthesis led to determination of the configuration of carmabin A and reassignment of the configuration of dragomabin at the stereogenic centre on the alkyne-bearing fragment.
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