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N terminal N-methylation modulates chiral centre induced helical (CIH) peptides' biophysical properties.

Wenjun Li, Kuan Hu, Qingzhou Zhang, Dongyuan Wang, Yue Ma, Zhanfeng Hou, Feng Yin, Zigang Li
Chemical Communications : Chem Comm 2018 Februrary 16
The effects of N-methylation on CIH peptides' biophysical properties were systematically studied. N-Methylation at the N terminal NH could help improve the peptides' cellular uptake with a retained helical conformation. This N-methylation strategy could also be applied to longer peptides to improve their stability and cellular uptake.

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