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Zinc-promoted cyclization of tosylhydrazones and 2-(dimethylamino)malononitrile: an efficient strategy for the synthesis of substituted 1-tosyl-1H-pyrazoles.

Bang-Hong Zhang, Lin-Sheng Lei, Si-Zhan Liu, Xue-Qing Mou, Wei-Ting Liu, Shao-Hua Wang, Jie Wang, Wen Bao, Kun Zhang
Chemical Communications : Chem Comm 2017 July 28
A Zn(OTf)2 -promoted cyclization reaction of tosylhydrazones with 2-(dimethylamino)malononitrile has been successfully developed providing an efficient strategy for the synthesis of substituted 1-tosyl-1H-pyrazoles.

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