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Breathing-induced new phase transition in an MIL-53(Al)-NH 2 metal-organic framework under high methane pressures.
Chemical Communications : Chem Comm 2017 July 19
The high pressure methane sorption tests on a flexible metal-organic framework [MIL-53(Al)-NH2 ] reveal a new phase transition to a large pore (lp) phase above 45 bar. The mixed-ligand strategy and pressure cycling tests are suggested to reduce the pressure requirement of such a phase transition for applications in natural gas storage.
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