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A deciduous directing group approach for the addition of aryl and vinyl nucleophiles to maleimides.

Kiran R Bettadapur, Veeranjaneyulu Lanke, Kandikere Ramaiah Prabhu
Chemical Communications : Chem Comm 2017 June 7
A Rh(iii)-catalyzed C-H activation followed by conjugate addition to maleimides, using carboxylic acid as a traceless/deciduous directing group, to formally furnish a Csp2 -Csp3 bond is presented. For the first time, derivatives of acrylic acid have been shown as surrogates for the unstable and expensive alkenyl boronic acids.

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