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Hierarchical self-supported ZnAlEu LDH nanotubes hosting luminescent CdTe quantum dots.

Alysson F Morais, Ivan G N Silva, Sreeprasanth P Sree, Fernando M de Melo, Gert Brabants, Hermi F Brito, Johan A Martens, Henrique E Toma, Christine E A Kirschhock, Eric Breynaert, Danilo Mustafa
Chemical Communications : Chem Comm 2017 June 30
Self-supported oligo-layered ZnAlEu LDH nanotubes (∅ 20 nm) self-assemble upon controlled hydrolysis of the metal ions (Zn2+ , Al3+ , Eu3+ ) in the presence of 1,3,5-benzenetricarboxylate anions and non-ionic worm-like micelles. Their high surface area and easily accessible cylindrical mesopores (175 m2 g-1 ; 0.75 cm3 g-1 ) facilitate interaction with 5 nm CdTe quantum dots, enhancing the overall luminescence behavior.

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