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Journal Article
Research Support, Non-U.S. Gov't
Review
Practical Synthesis of both Enantiomeric Amino Acid, Mannich, and Aldol Derivatives by Asymmetric Organocatalysis.
Chemical Record : An Official Publication of the Chemical Society of Japan ... [et Al.] 2017 October
In this account, we describe our recent developments in organocatalyzed asymmetric methodologies for the practical synthesis of both enantiomers. The synthesis of both enantiomeric products by using both enantiomeric catalysts is the most traditional way. In addition, use of two pseudoenantiomeric catalysts provides a more practical approach for the synthesis of both enantiomeric products. Even more efficient is the use of a single enantiomeric catalyst in the presence or absence of certain additives for obtaining both enantiomeric products. These three different strategies are illustrated by using certain organocatalyzed asymmetric approaches.
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