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Switching chirality in the assemblies of bio-based amphiphiles solely by varying their alkyl chain length.
Chemical Communications : Chem Comm 2017 Februrary 10
Here we show that chirality inversion can be realized solely by changing the alkyl chain length of sorbitol-alkylamine surfactants. The chirality switch phenomenon is attributed to twisting of a headgroup, which depends on the balance between hydrophobic interaction and torsional stress, resulting in various orientational orders in assemblies and chirality inversion.
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