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Water-induced helical supramolecular polymerization and gel formation of an alkylene-tethered perylene bisimide dyad.

Xu Lin, Hiroki Kurata, Deepak D Prabhu, Mitsuaki Yamauchi, Tomonori Ohba, Shiki Yagai
Chemical Communications : Chem Comm 2016 December 21
An alkylene-tethered perylene bisimide (PBI) dyad with hydrophilic substituents forms helical supramolecular polymers that can be visualized by AFM in THF-water mixtures. The supramolecular polymers also form thixotropic gel-like lyotropic mesophases in the mixtures.

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