Oriented Metal-organic Framework Membranes for Molecular Separations.

Metal-organic framework (MOF) membranes, which are recognized as state-of-the-art platforms applied in various separation processes, have attracted widespread attention. Nonetheless, to overcome the trade-off between permeability and selectivity, which is crucial for achieving efficient separation, it is important to rationally design and manipulate MOF membrane structure. Given remarkable advances in the past decade, a timely summary of recent advancement in this field has become indispensable. This review introduces major strategies for fabricating oriented MOF membranes, including in situ growth, contra-diffusion method, interface-assisted approach, and laminated nanosheet assembly. New insights into their updated progress and potential are elucidated. Of particular note, recent development and emerging applications of oriented MOF membranes, illustrating their potential to address environmental and energy challenges, are highlighted. Finally, remaining challenges facing their bath production and practical applications are discussed.