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Paired Electrolysis-Enabled Arylation of Quinoxalin-2(1 H )-ones.
Journal of Organic Chemistry 2024 April 25
The first paired electrolysis-enabled arylation of quinoxalin-2(1 H )-ones was achieved using cyanoarenes as the arylation reagents. A variety of 3-arylquinoxalin-2(1 H )-ones with various important functional groups were obtained in moderate to good yields under metal- and chemical oxidant-free conditions. With a pair of reductive and oxidative processes occurring among the substrates and reaction intermediates, the power consumption can be dramatically reduced.
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