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Gold-Catalyzed Reactions of Enynals with Alkenes for Synthesis Binaphthyl Derivatives.
Journal of Organic Chemistry 2024 April 17
A PPh3 Au[B(C6 F5 )4 ]-catalyzed reaction of enynals and alkenes for the construction of binaphthyl derivatives was described. This transformation was achieved through o -Quinodimethane ( o -QDM) intermediate's extended conjugated addition process. The reaction has the advantages of wide substrate scopes, mild reaction conditions, high efficiency, and good scalability.
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