We have located links that may give you full text access.
Pd-catalyzed three-component [2 + 2 + 1] cycloamination toward carbazoles.
Organic & Biomolecular Chemistry 2024 April 4
Conventional approaches using hydroxylamine derivatives as single nitrogen sources for the preparation of N-heterocyclic molecules rely on two chemical processes involving sequential nucleophilic and electrophilic C-N bond formations. Herein, we report a novel Suzuki reaction/C-H activation/amination sequence for building a myriad of carbazoles in a single transformation using bifunctional secondary hydroxylamines. It is noteworthy that the synthetic utility of this methodology is highlighted by the total synthesis of clausine V and glycoborine by incorporating the title [2 + 2 + 1] cycloamination as the key step. Control experiments were performed to gain a better understanding of the reaction mechanism.
Full text links
Related Resources
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app
All material on this website is protected by copyright, Copyright © 1994-2024 by WebMD LLC.
This website also contains material copyrighted by 3rd parties.
By using this service, you agree to our terms of use and privacy policy.
Your Privacy Choices
You can now claim free CME credits for this literature searchClaim now
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app