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Asymmetric, Remote C(sp 3 )-H Arylation via Sulfinyl-Smiles Rearrangement.
Angewandte Chemie 2024 March 21
An efficient asymmetric remote arylation of C(sp3 )-H bonds under photoredox conditions is described here. The reaction features the addition radicals to a double bond followed by a site-selective radical translocation (1,n-hydrogen atom transfer) as well as a stereocontrolled aryl migration via sulfinyl-Smiles rearrangement furnishing a wide range of chiral α-arylated amides with up to >99 : 1 er. Mechanistic studies indicate that the sulfinamide group governs the stereochemistry of the product with the aryl migration being the rate determining step preceded by a kinetically favored 1,n-HAT process.
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