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A Ring Expansion Approach To N -oxy-2,5-diketopiperazines.

Amy C Jackson, James T Olsen, Sasha Sundstrom, Kyle M Lambert, John L Wood
Tetrahedron Letters 2022 June 9
A ring expansion of tetramic acids (pyrrolidine-2,4-diones) to N -oxy-2,5-diketopiperazines (DKPs) is described. This method allows for the facile and late-stage construction of the hydroxamic acid moiety and can thereby serve as a general method for accessing N -oxy-2,5-DKP natural products.

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