CB 11 H 10 - and Related Carborenes.

Starting with HOOC-CB11 Me11 - or CB11 Me12 - as the starting material, collision-induced dissociation has produced a series of methylated analogs of didehydro- closo -carbadodecaborane anions by sequential losses of up to 5 equiv of ethylene. These reactive intermediates are carborane analogues of doubly pyramidalized alkenes and, more distantly, arynes. Density functional theory calculations have been used to develop a proposal for the mechanism of the unusual formation of ethylene from the carborane methyl substituents.