Mn-CeOx/MeOx(Ti, Al)/cordierite preparation with ultrasound-assisted for non-methane hydrocarbon removal from cooking oil fumes.

Cooking oil fumes (COFs) which contains a variety of volatile organic compounds (VOCs) is noxious not only to the environment but also to human health. Among COFs, the Non-methane Hydrocarbon (NMHC) removal rate is an index of the removal rate of COFs in the latest COFs purification standard (DB 11/1488-2018). Ultrasonic treatment can assist the synthesis of catalysts by creating "cavitation", which can improve the surface microtopography of catalysts. The research results in this paper revealed that the NMHC conversion of catalysts with ultrasonic treatment increased significantly. Besides, the samples that coated TiO2 had a higher conversion of NMHC than that coated Al2 O3 because TiO2 has better oxidation performance than Al2 O3 . According to the XPS, SEM, EDS and BET data, because of the enhancement of interaction of the active components of catalysts caused by ultrasonic intervention, T-UU-CTAB exhibited the best catalytic performance, which attributed to the high levels of Mn4+ /Mn3+ , Ce4+ /Ce3+ and Oads /Olatt , more developed pore structure owing to the smaller particle size, higher dispersion of active components, larger specific surface area and larger total pore volume produced by the ultrasonic treatment. Moreover, the conversion of NMHC over T-UU-CTAB is 93.6% at 400 °C.