We have located links that may give you full text access.
Tetranuclear cobalt(ii)-isonicotinic acid frameworks: selective CO 2 capture, magnetic properties, and derived "Co 3 O 4 " exhibiting high performance in lithium ion batteries.
Two new 3D cobalt metal-organic frameworks (MOFs), [Co4(CH3COO)(in)5(μ3-OH)2]·2H2O (1) and [Co4(SO4)2(in)4(DMF)2]·3DMF (2) (Hin = isonicotinic acid), have been prepared through the anion template method. Compound 1 consists of rare odd-number connected (9-connected) cubane-like SBUs, while compound 2 consists of 8-connected high-symmetry square-planar clusters. Magnetic studies indicate that compound 1 exhibits spin-canting antiferromagnetic ordering, while compound 2 shows antiferromagnetic behavior. At 273 K and 1 bar, compound 1 exhibits a high CO2 selectivity over CH4 and a significant CO2 uptake of 13.6 wt%, which is higher than that of 2 (8.5 wt%). Furthermore, compound 1 was then transformed into ultrasmall Co3O4 nanoparticles via simple but effective annealing treatment. Electrochemical measurements show that the Co3O4 nanospheres derived from compound 1 exhibited high and stable lithium storage properties (1100 mA h g-1 after 100 cycles at 200 mA g-1) and excellent rate capabilities.
Full text links
Related Resources
Trending Papers
Heart failure with preserved ejection fraction: diagnosis, risk assessment, and treatment.Clinical Research in Cardiology : Official Journal of the German Cardiac Society 2024 April 12
Proximal versus distal diuretics in congestive heart failure.Nephrology, Dialysis, Transplantation 2024 Februrary 30
Efficacy and safety of pharmacotherapy in chronic insomnia: A review of clinical guidelines and case reports.Mental Health Clinician 2023 October
World Health Organization and International Consensus Classification of eosinophilic disorders: 2024 update on diagnosis, risk stratification, and management.American Journal of Hematology 2024 March 30
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app
All material on this website is protected by copyright, Copyright © 1994-2024 by WebMD LLC.
This website also contains material copyrighted by 3rd parties.
By using this service, you agree to our terms of use and privacy policy.
Your Privacy Choices
You can now claim free CME credits for this literature searchClaim now
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app