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Selective encapsulation and separation of dihalobenzene isomers with discrete heterometallic macrocages.
Chemistry : a European Journal 2018 November 15
A series of metallosupramolecular architectures have been prepared including rectangles, prisms and cages, and featuring half-sandwich rhodium(III) fragments at the vertices. Remarkably, a stable cage-like heteropolymetallic complex possessing eight rhodium(III) and two silver(I) metal ions (3) has been obtained following a multistep procedure. The RhIII/AgI mixed macrocage enables the separation of dihalogenated benzene derivatives with high selectivity. Furthermore, a detailed X-ray crystallographic study confirmed that the discriminative encapsulation of para-dihalobenzene (dichlorobenzene, dibromobenzene and diiodobenzene) is favored by Ag-π interactions and steric effects.
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