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Structure stabilization effect of configuration entropy in cubic WN.

The microscopic structure of cubic WN has been studied combining scanning transmission electron microscopy and first-principles calculations. Because of the contribution of configurational entropy, NaCl-type WN with disordered vacancies becomes more stable at high temperatures than NbO-type WN. Moreover, electron beam irradiation can induce an order-disorder transition in cubic WN. It is suggested that the ordered NbO-type WN can be obtained after annealing below the transition temperature. The results shed light on the stability of materials synthesized at high pressures and high temperatures.

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