Enhancement of 1.5 μm fluorescence signal from Er 3+ due to Yb 3+ in yttrium silicate powders pumped at 975 and 808 nm.

The effect of the presence of ytterbium (Yb3+ ) on the near-infrared (NIR) emission profile of erbium (Er3+ ), more specifically the 4 I13/2  → 4 I15/2 radiative transition around 1.5 μm, in yttrium silicate crystalline ceramic powders prepared by combustion synthesis was investigated under different NIR laser excitation wavelengths (λ = 808 and 975 nm). Enhancement of fluorescence around 1.5 μm due to the presence of Yb3+ was observed, which has potential use in medicine (NIR-III biological window) and optical communications (C-band transmission window). Two different excitation channels involving energy transfer between Er3+ and Yb3+ were studied: one involving the sensitization of Er3+ by Yb3+ (for λ = 975 nm laser light excitation) and the other involving direct excitation of Er3+ with Yb3+ acting as an energy reservoir (for λ = 808 nm laser light excitation). The energy transfer mechanisms of both processes are discussed in the text.