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Isocyanide insertion into Au-H bonds: first gold iminoformyl complexes.
Chemical Communications : Chem Comm 2018 October 10
Isocyanides insert into gold(iii)-hydrogen bonds to give the first examples of gold iminoformyl complexes. The reaction is initiated by catalytic amounts of radicals; DFT calculations indicate that this is an equilibrium reaction driven forward by isocyanide in sufficient excess to trap the Au(ii) intermediate.
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