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Na 1.85 Mg 1.85 In 1.15 (PO 4 ) 3 and Ag 1.69 Mg 1.69 In 1.31 (PO 4 ) 3 with alluaudite-type structures.

Single crystals of two new phosphates, sodium magnesium indium(III) tris-(orthophosphate) and silver magnesium indium(III) tris-(orthophosphate), were obtained from solid-state reactions. The two phosphates are isotypic and exhibit alluaudite-type structures. They are characterized by a cationic disorder of the Mg and In sites and a partial occupation of the Na and Ag sites, respectively. The structure of both phosphates is made up of chains of edge-sharing [(Mg,In)O6 ] octa-hedra extending parallel to [10]. Adjacent chains are linked by PO4 tetra-hedra to form a three-dimensional framework delimiting two types of channels parallel to [001] in which the monovalent cations are situated. The coordination numbers of the Na+ cations are 6 and 8, and for both Ag+ cations 6. The corresponding coordination spheres are considerably distorted.

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