JOURNAL ARTICLE
RESEARCH SUPPORT, NON-U.S. GOV'T
Add like
Add dislike
Add to saved papers

A thermally stable three-dimensional cobalt(II) coordination polymer based on the V-shaped ligand 4-(4-carboxyphenoxy)isophthalate.

A new cobalt(II) coordination polymer (CP), poly[[bis[μ6 -4-(4-carboxylatophenoxy)benzene-1,3-dicarboxylato-κ6 O1 :O1 :O3 :O3' :O4 :O4' ]bis(1,10-phenanthroline-κ2 N,N')tricobalt(II)] 0.72-hydrate], {[Co3 (C15 H7 O7 )2 (C12 H8 N2 )2 ]·0.72H2 O}n , (I), is constructed from CoII ions and 4-(4-carboxyphenoxy)isophthalate (cpoia3- ) and 1,10-phenanthroline (phen) ligands. Based on centrosymmetric trinuclear [Co3 (phen)2 (COO)6 ] secondary building units (SBUs), the structure of (I) is a three-dimensional CP with a (3,6)-connected net and point symbol (42 .6)2 (44 .62 .87 .102 ). The positions of four [Co3 (phen)2 (COO)6 ] SBUs and four cpoia3- ligands reproduce a Chinese-knot-shaped arrangement along the ab plane. (I) has been characterized by single-crystal X-ray diffraction, IR spectroscopy, powder X-ray diffraction (PXRD) and thermostability analysis. It shows a good thermal stability from room temperature to 673 K. In addition, the temperature dependence of the magnetic properties was measured.

Full text links

We have located links that may give you full text access.
Can't access the paper?
Try logging in through your university/institutional subscription. For a smoother one-click institutional access experience, please use our mobile app.

For the best experience, use the Read mobile app

Mobile app image

Get seemless 1-tap access through your institution/university

For the best experience, use the Read mobile app

All material on this website is protected by copyright, Copyright © 1994-2024 by WebMD LLC.
This website also contains material copyrighted by 3rd parties.

By using this service, you agree to our terms of use and privacy policy.

Your Privacy Choices Toggle icon

You can now claim free CME credits for this literature searchClaim now

Get seemless 1-tap access through your institution/university

For the best experience, use the Read mobile app