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Metal coordination induced ring contraction of porphyrin derivatives.
Chemical Communications : Chem Comm 2018 August 31
A remarkable rearrangement of a diferrocenylporphyrin to give a silver(iii) corrole has been discovered. Compared to the previously reported porphyrin to corrole ring conversions (extremely rare and poor reaction yields), our methodology delivers near quantitative yield for this ring contraction.
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