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Comparing Protonolysis and Transmetalation Reactions: Microcalorimetric Studies of C-Au I Bonds in [AuRL] Complexes.
Inorganic Chemistry 2018 September 5
The protonolysis of C-Au bonds in [AuRL] organometallic complexes has been studied by calorimetry for 12 R groups. The experimental data have been combined with density functional theory calculations to obtain bond dissociation energy (BDE) values. The C-Au BDE values show a good correlation with the corresponding isolobal C-H BDE values. The heat released in the protonolysis of [AuRL] has also been measured for R = Ph and L = P(OPh)3 , PPh3 , PMe3 , PCy3 , and IPr, and these values strongly depend on the trans influence of L because of the mutual destabilization of the L-Au and Au-C bonds. The enthalpies of the transmetalation reaction [AuR(PPh3 )] + SnIBu3 → [AuI(PPh3 )] + SnRBu3 for seven R groups have been measured and compared with those of the corresponding [AuR(PPh3 )] protonolysis.
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