We have located links that may give you full text access.
Synthesis and Characterization of Self-Assembled Chiral Fe II 2 L 3 Cages.
Chemistry : a European Journal 2018 October 2
We present here the synthesis of chiral BINOL-derived (BINOL=1,1'-bi-2-naphthol) bisamine and bispyridine-aldehyde building blocks that can be used for the self-assembly of novel chiral FeII 2 L3 cages when mixed with an iron(II) precursor. The properties of a series of chiral cages were studied by NMR and circular dichroism (CD) spectroscopy, cold-spray ionization MS, and molecular modeling. Upon formation of the M2 L3 cages, the iron corners can adopt various isomeric forms: mer, fac-Δ, or fac-Λ. We found that the coordination geometry around the metal centers in R-Cages 1 and 2 were influenced by the chiral BINOL backbone only to a limited extent, as a mixture of cages was formed with fac and mer configurations at the iron corners. However, single cage species (fac-RR-Cage and fac-RS-Cage) that are enantiopure and highly symmetric were obtained by generating these chiral M2 L3 cages by using the bispyridine-aldehyde building blocks in combination with chiral amine moieties to form pyridylimine ligands for coordination to iron. Next to consistent NMR spectra, the CD spectra confirm the configurations fac-(Λ,Λ) and fac-(Δ,Δ) corresponding to RR- and RS-Cage, respectively.
Full text links
Related Resources
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app
All material on this website is protected by copyright, Copyright © 1994-2024 by WebMD LLC.
This website also contains material copyrighted by 3rd parties.
By using this service, you agree to our terms of use and privacy policy.
Your Privacy Choices
You can now claim free CME credits for this literature searchClaim now
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app