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Novel Composite Electrolytes of Zr 0.92 Y 0.08 O 2-α (8YSZ)-Low Melting Point Glass Powder for Intermediate Temperature Solid Oxide Fuel Cells.

Materials 2018 July 17
In this study, Zr0.92 Y0.08 O2-α (8YSZ) powders were synthesized by the sol-gel method. The chemical physics changes and phase formation temperature of 8YSZ crystal were determined by thermogravimetry analysis and differential scanning calorimetry (TGA-DSC). 8YSZ-low melting point glass powder (8YSZ-glass) composite electrolytes with various weight ratios were prepared and calcined at different temperatures. The X-ray diffraction (XRD) patterns of the composite electrolytes were tested. The effects of synthesis temperature, weight ratio, test temperature, and oxygen partial pressure on the conductivities of 8YSZ-glass composite electrolytes, were also investigated at 400⁻800 °C. The result of the log σ ~ log( p O₂) plot indicates that the 8YSZ-20% glass (700 °C) is almost a pure ionic conductor. The oxygen concentration discharge cell illustrates that the 8YSZ-20% glass (700 °C) composite electrolyte is a good oxygen ion conductor.

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