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Crystal structure of ( E )-2-( tert -butyl-amino)-4-( tert -butyl-imino)-naphthalen-1(4 H )-one.
The title compound, C18 H24 N2 O, is the first example of a naphtho-quinone imine derivative isolated in the 4-imine/2-amine tautomeric form having bulky alkyl substituents at the N atoms. The mol-ecular conformation is stabilized by an intra-molecular hydrogen bond between the amine and a carbonyl group and by London attraction between the two tert -butyl groups. Only van der Waals inter-actions were identified in the crystal packing.
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