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Symmetry breaking by enzyme-catalyzed epoxide hydrolysis.
IUCrJ 2018 July 2
Janfalk Carlsson et al. [ IUCrJ (2018), 5 , 269-282] describe studies on factors determining selective ring opening of methylstyrene oxide stereoisomers by the epoxide hydrolase StEH1. The stereo-differentiating step is selective hydrolysis of an alkylated intermediate formed by reaction of the epoxide with an aspartyl residue.
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