We have located links that may give you full text access.
Ultrafast Ground-State Intramolecular Proton Transfer in Diethylaminohydroxyflavone Resolved with Pump-Dump-Probe Spectroscopy.
Journal of Physical Chemistry Letters 2018 August 3
4'- N, N-Diethylamino-3-hydroxyflavone (DEAHF), due to excited-state intramolecular proton transfer (ESIPT) reaction, exhibits two solvent-dependent emission bands. Because of the slow formation and fast decay of the ground-state tautomer, its population does not accumulate enough for its detection during the normal photocycle. As a result, the details of the ground-state intramolecular proton-transfer (GSIPT) reaction have remained unknown. The present work uses femtosecond pump-dump-probe spectroscopy to prepare the short-lived ground-state tautomer and track this GSIPT process in solution. By simultaneously measuring femtosecond pump-probe and pump-dump-probe spectra, ultrafast kinetics of the ESIPT and GSIPT reactions are obtained. The GSIPT reaction is shown to be a solvent-dependent irreversible two-state process in two solvents, with estimated time constants of 1.7 ps in toluene and 10 ps in the more polar tetrahydrofuran. These results are of great value in both fully describing the photocycle of this four-level proton transfer molecule and for providing a deeper understanding of dynamical solvent effects on tautomerization.
Full text links
Related Resources
Trending Papers
Challenges in Septic Shock: From New Hemodynamics to Blood Purification Therapies.Journal of Personalized Medicine 2024 Februrary 4
Molecular Targets of Novel Therapeutics for Diabetic Kidney Disease: A New Era of Nephroprotection.International Journal of Molecular Sciences 2024 April 4
The 'Ten Commandments' for the 2023 European Society of Cardiology guidelines for the management of endocarditis.European Heart Journal 2024 April 18
A Guide to the Use of Vasopressors and Inotropes for Patients in Shock.Journal of Intensive Care Medicine 2024 April 14
Diagnosis and Management of Cardiac Sarcoidosis: A Scientific Statement From the American Heart Association.Circulation 2024 April 19
Essential thrombocythaemia: A contemporary approach with new drugs on the horizon.British Journal of Haematology 2024 April 9
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app
All material on this website is protected by copyright, Copyright © 1994-2024 by WebMD LLC.
This website also contains material copyrighted by 3rd parties.
By using this service, you agree to our terms of use and privacy policy.
Your Privacy Choices
You can now claim free CME credits for this literature searchClaim now
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app