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Highly Lewis acidic cationic alkaline earth metal complexes.
Chemical Communications : Chem Comm 2018 August 15
Cationic Lewis base-free β-diketiminate (BDI) complexes of Mg and Ca have been isolated as their B(C6 F5 )4 - salts. The cation (BDI)Mg+ shows an extraordinarily strong Lewis acidity that can compete with strong Lewis acids like B(C6 F5 )3 and (BDI)AlMe+ . Its highly electrophilic nature is exemplified by isolation of an 3-hexyne adduct.
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