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Copper-catalysed regioselective sulfenylation of indoles with sodium sulfinates.

Xiaojun Luo, Qiang Liu, Hongxia Zhu, Huoji Chen
Royal Society Open Science 2018 May
A copper-catalysed sulfenylation of indoles with sodium sulfinates that affords 3-sulfenylindoles in good-to-excellent yields in N , N -dimethyl formamide (DMF) is described. In the process, DMF serves not only as a solvent but also as a reductant. This transformation is easy to carry out and has mild reaction conditions and good functional group tolerance.

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