JOURNAL ARTICLE
RESEARCH SUPPORT, NON-U.S. GOV'T
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Hydrogen bonding and fluorous weak interactions in the non-isomorphous {4,4'-bis[(2,2,3,3-tetrafluoropropoxy)methyl]-2,2'-bipyridine-κ 2 N,N'}dibromidopalladium and -platinum complexes.

The polyfluorinated title compounds, [MBr2 (C18 H16 F8 N2 O2 )] or [4,4'-(HCF2 CF2 CH2 OCH2 )2 -2,2'-bpy]MBr2 , (1) (M = Pd and bpy is bipyridine) and (2) (M = Pt), have -CH(α)2 OCH(β)2 CF2 CF2 H side chains with methylene H-atom donors at the α and β sites, and methine H-atom donors at the terminal sites, in addition to aromatic H-atom donors. In contrast to the original expectation of isomorphous structures, (1) crystallizes in the space group C2/c and (2) in P21 /n, with similar unit-cell volumes and Z = 4. The asymmetric unit of (1) is one half of the molecule, which resides on a crystallographic twofold axis. Both (1) and (2) display stacking of the molecules, indicating a planar (bpy)MBr2 skeleton in each case. The structure of (1) exhibits columns with C-H(β) ...Br hydrogen bonds between consecutive layers which conforms to a static (β,β) linkage between layers. In the molecular plane, (1) shows double C-H(α) ...Br hydrogen bonds self-repeating along the b axis, the planar molecules being connected into infinite belts. Compound (2) has no crystallographic symmetry and forms π-dimer pairs as supermolecules, which then stack parallel to the a axis. The π-dimer-pair supermolecules exhibit (Pt-)Br...Br(-Pt) contacts [3.6937 (7) Å] to neighbouring π-dimer pairs crosslinking the columns. The structure of (2) reveals many C-H...F(-C) interactions between F atoms and aromatic C-H groups, in addition to those between F atoms and methylene C-H groups.

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