Optimization adsorption of norfloxacin onto polydopamine microspheres from aqueous solution: Kinetic, equilibrium and adsorption mechanism studies.

Polydopamine microspheres (PDMPs) synthesized by a facile solution oxidation method were adopted as a potential adsorbent for the removal of Norfloxacin (NOR) from aqueous solution. The morphologies and properties of PDMPs were characterized using TEM, SEM, FTIR and pHPZC . Parameters effects such as contact time, initial pH, initial concentration and ionic strength on the adsorption capacity of NOR onto PDMPs were studied. To maximize NOR removal from liquid phase, Box-Behnken experimental design (BBD) combined with response surface modeling (RSM) was employed based on the 17 preliminary experiments at 308 K. Optimum contact time, initial NOR concentration and initial pH value were found to be 97 min, 303 mg·L-1 and 6.6, respectively, the corresponding NOR removal capacity was found to be 307 mg·g-1 . Batch adsorption experiments under the optimal conditions were conducted to investigate kinetics, thermodynamics and adsorption isotherm. Kinetic analysis confirmed that the kinetic data were well described by Pseudo-second order model. The experimental equilibrium data were well fitted by Langmuir, Redlich-Peterson, Koble-Corrigan and Dubinin-Radushkevich models. Thermodynamic parameters such as Gibbs free energy, enthalpy and entropy were calculated and the results indicated that the NOR adsorption onto PDMPs was spontaneous and endothermic. The adsorption process may be attributed to the electrostatic interaction, the formation of hydrogen bonds or π-π stacking interactions among the polydopamine (PDA) and NOR molecule.